It might look like it makes no difference, but think about this:
1 phonecall = 100Kb/s
1 file transfer = 600Mb/s
The packets in the phonecall get marked with DSCP 46 and are assigned to Queue5 with a weight of 1
The packets in the file transfer get marked with DSCP of 0 and are assigned to queue0 with a weight of 1
The switch now devotes the *same* amount of resources to switching the VoIP packets as they do to switching the other packets.
In other words, the switch will be forwarding all VoIP packets as soon as it is already forwarding 0.02% of the file transfer packets.
You can change the "weight" if you like, but don't bother unless you've added up your bandwidth requirements and you have a specific goal in mind.