Ok, it's easy. You just need to create a new VLAN ID, then assign to it a new IP address, as following:
vlan 254
name <name>
interface vlan 254
ip address <ip_address> <subnet_mask>
description <description>
In the trunk ports, you need to proceed as the last post:
port link-type trunk
port trunk permit vlan <permitted_vlans plus 254>
port trunk pvid vlan 254
Keep in mind that the 4500 switches only supports up to 4 VLAN interfaces (Layer 3). It supports up to 256 VLAN ID (Layer 2) but only 4 IP addresses.
The 5500-EI can support much more: up to 64 IP addresses.
Regards